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Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
- Source :
- RSC advances. 8(66)
- Publication Year :
- 2018
-
Abstract
- The combination of continuous flow technology with immobilizing of only 0.13 mol% of triflic acid (TfOH) on silica-encapsulated superparamagnetic iron oxide nanoparticles (SPIONs) under solvent-free conditions successfully provided a powerful, efficient, and eco-friendly route for the synthesis of plasticizers. The turnover frequency value in micro-flow conditions varied in the range of 948.7 to 7384.6 h−1 compared to 403.8 to 3099 h−1 for in-flask. This technique works efficiently, encouraging future applications of micro-flow nano-catalysis in green chemistry.
- Subjects :
- Green chemistry
Materials science
Superparamagnetic iron oxide nanoparticles
010405 organic chemistry
Continuous flow
General Chemical Engineering
Flow (psychology)
Plasticizer
Nanotechnology
General Chemistry
010402 general chemistry
01 natural sciences
0104 chemical sciences
Catalysis
chemistry.chemical_compound
chemistry
Triflic acid
Subjects
Details
- ISSN :
- 20462069
- Volume :
- 8
- Issue :
- 66
- Database :
- OpenAIRE
- Journal :
- RSC advances
- Accession number :
- edsair.doi.dedup.....9b657a04d0c1b33defa378a8f6c5b8d1