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Reactions of Highly Branched Fluoroolefins with Methyllithium and Methylmagnesium Bromide: Formations of Unexpected Polyfluorocyclobutene and Polyfluoropentadiene Compounds
- Source :
- ChemInform. 34
- Publication Year :
- 2003
- Publisher :
- Wiley, 2003.
-
Abstract
- Introduction of a methyl group into hexafluoropropene trimers was achieved by reactions with organometallic carbon nucleophiles. Unusual cyclization and defluorination occurred simultaneously with a formation of methylated polyfluoroolefins: excess methyllithium provided a polyfluorocyclobutene compound, while a polyfluoropentadiene derivative was formed by use of excess methyllithium.
- Subjects :
- Organic Chemistry
chemistry.chemical_element
Halogenation
General Medicine
Grignard reagent
Organolithium reagent
Biochemistry
Medicinal chemistry
Inorganic Chemistry
chemistry.chemical_compound
Nucleophile
chemistry
Bromide
Environmental Chemistry
Organic chemistry
Methyllithium
Physical and Theoretical Chemistry
Carbon
Derivative (chemistry)
Methyl group
Subjects
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 34
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi.dedup.....9b6db1fa7c845cf768f395c3d12f6e6a