Single-particle configurations of the excited states of Po203

Excited states of the $^{203}$Po ($Z = 84, N = 119$) have been investigated after populating them through $^{194}$Pt($^{13}$C,4n) fusion-evaporation reaction at E$_{beam}$ = 74 MeV and using a large array of Compton suppressed HPGe clover detectors as the detection setup for the emitted $\gamma$-rays. Standard techniques of $\gamma$-ray spectroscopy have been applied towards establishing the level structure of the nucleus. Twenty new $\gamma$-ray transitions have been identified therein, through $\gamma-\gamma$ coincidence measurements, and spin-parity assignments of several states have been determined or confirmed, following the angular correlation and linear polarization measurements on the observed $\gamma$-rays. The excited states have been interpreted in the framework of large basis shell model calculations, while comparing their calculated and experimental energies. They have been principally ascribed to proton population in the $h_{9/2}$ and $i_{13/2}$ orbitals outside the $Z = 82$ closure and neutron occupation of the $f_{5/2}$, $p_{3/2}$ and $i_{13/2}$ orbitals in the $N = 126$ shell.