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A trinuclear Cu(II) precursor for solvatochromically distinguishing CH3OH from C2H5OH
- Publication Year :
- 2019
- Publisher :
- Taylor & Francis, 2019.
-
Abstract
- In order to develop an easy and rapid identification method for distinguishing CH3OH from C2H5OH, a new carbonate-based trinuclear Cu(II) precursor, [Cu3(bpy)6(μ3-CO3)(CH3OH)](BF4)4·(CH3OH)2·(H2O)2 (1), has been isolated. We report here the synthesis, crystal structure, and characterizations by various spectroscopic (IR, UV–Vis, powder XRD) techniques, as well as the solvatochromic behavior of this coordination compound. Its X-ray crystal structure reveals that the main structure of 1 consists of three [(bpy)2Cu]2+ centers, which are bridged by carbonate via a μ3-η1,η1,η1 fashion. Strong O–H⋯O hydrogen bonding between the carbonate and solvent molecules has been observed for the first time in similar structures. Its ground powder exhibits solvatochromic behavior that selectively distinguishes CH3OH from C2H5OH.
- Subjects :
- Chemistry
Hydrogen bond
Solvatochromism
chemistry.chemical_element
010402 general chemistry
010403 inorganic & nuclear chemistry
01 natural sciences
Copper
0104 chemical sciences
Rapid identification
chemistry.chemical_compound
Materials Chemistry
Physical chemistry
Carbonate
Physical and Theoretical Chemistry
Subjects
Details
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....9cb58b4be2857f175385eba043195f9d
- Full Text :
- https://doi.org/10.6084/m9.figshare.11481609