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Solvated-electron production using cyanocuprates is compatible with the UV-environment on a Hadean-Archaean Earth

Authors :
Jack W. Szostak
Sukrit Ranjan
Albert C. Fahrenbach
Christopher J. Magnani
Dimitar Sasselov
Anders Björkbom
Zoe R. Todd
Source :
Chemical communications (Cambridge, England). 54(9)
Publication Year :
2018

Abstract

UV-driven photoredox processing of cyanocuprates can generate simple sugars necessary for prebiotic synthesis. We investigate the wavelength dependence of this process from 215 to 295 nm and generally observe faster rates at shorter wavelengths. The most efficient wavelengths are accessible to a range of potential prebiotic atmospheres, supporting the potential role of cyanocuprate photochemistry in prebiotic synthesis on the early Earth.

Details

ISSN :
1364548X
Volume :
54
Issue :
9
Database :
OpenAIRE
Journal :
Chemical communications (Cambridge, England)
Accession number :
edsair.doi.dedup.....9d3fc2c75f0bdbab30bc30610b9ee1d4