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Reactivity studies of pincer bis-protic N-heterocyclic carbene complexes of platinum and palladium under basic conditions
- Source :
- Beilstein Journal of Organic Chemistry, Beilstein Journal of Organic Chemistry, Vol 12, Iss 1, Pp 1334-1339 (2016)
- Publication Year :
- 2016
- Publisher :
- Beilstein-Institut, 2016.
-
Abstract
- Bis-protic N-heterocyclic carbene complexes of platinum and palladium (4) yield dimeric structures 6 when treated with sodium tert-butoxide in CH2Cl2. The use of a more polar solvent (THF) and a strong base (LiN(iPr)2) gave the lithium chloride adducts monobasic complex 7 or analogous dibasic complex 8.
- Subjects :
- NHC
chemistry.chemical_element
010402 general chemistry
01 natural sciences
Medicinal chemistry
Full Research Paper
lcsh:QD241-441
chemistry.chemical_compound
lcsh:Organic chemistry
Organic chemistry
Reactivity (chemistry)
platinum
lcsh:Science
protic N-heterocyclic carbene
Dibasic acid
010405 organic chemistry
Monobasic acid
Organic Chemistry
palladium
0104 chemical sciences
Pincer movement
15N NMR spectroscopy
Chemistry
chemistry
Lithium chloride
lcsh:Q
Platinum
Carbene
Palladium
Subjects
Details
- Language :
- English
- ISSN :
- 18605397
- Volume :
- 12
- Database :
- OpenAIRE
- Journal :
- Beilstein Journal of Organic Chemistry
- Accession number :
- edsair.doi.dedup.....9efa9d56150e3b65b0733ba0390cfcc8