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Alkaline-Metal-Catalyzed One-Pot Aminobenzylation of Aldehydes with Toluenes

Authors :
Guoqing Liu
Jianyou Mao
Patrick J. Walsh
Source :
Organic Letters. 21:8514-8518
Publication Year :
2019
Publisher :
American Chemical Society (ACS), 2019.

Abstract

A novel and easily accessible MN(SiMe3)2 (M = Li or Na)/Cs2CO3 co-catalyzed benzylation of in situ generated N-(trimethylsilyl) aldimines with toluene derivatives has been successfully developed. T...

Subjects

Subjects :
chemistry.chemical_classification
Aldimine
Trimethylsilyl
010405 organic chemistry
Organic Chemistry
010402 general chemistry
Alkali metal
01 natural sciences
Biochemistry
Toluene
0104 chemical sciences
Catalysis
chemistry.chemical_compound
chemistry
Organic chemistry
Physical and Theoretical Chemistry

Details

ISSN :
15237052 and 15237060
Volume :
21
Database :
OpenAIRE
Journal :
Organic Letters
Accession number :
edsair.doi.dedup.....a09d0cffbcee732d399d3063524b34c4
Full Text :
https://doi.org/10.1021/acs.orglett.9b02737
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