Stepwise Construction of Discrete Heterometallic Coordination Cages Based on Self-Sorting Strategy

Authors :: Zi-Wei Guo
Yue-Jian Lin
Hao Li
Ying-Feng Han
Guo-Xin Jin
Source :: Journal of the American Chemical Society. 136:2982-2985
Publication Year :: 2014
Publisher :: American Chemical Society (ACS), 2014.
Abstract: A chelation-directed self-sorting synthesis of a series of cationic heterometallic coordination cages (HCCs) with tunable sizes is described. Two complexation modes were found in the cage-forming process. Metal-anchoring host-guest behavior and size-selective in-cage catalytic activities were found for the HCCs.

Subjects :: Condensed Matter::Soft Condensed Matter
Colloid and Surface Chemistry
Self sorting
Chemistry
Physics::Atomic and Molecular Clusters
Cationic polymerization
Nanotechnology
General Chemistry
HCCS
Quantitative Biology::Other
Biochemistry
Combinatorial chemistry
Catalysis

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