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Crystal structure of dimethyl 2-((2 Z ,5 Z )-5-(2-methoxy-2-oxoethylidene)-2-{( E )-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate
- Source :
- Acta crystallographica. Section E, Crystallographic communications, Acta crystallographica. Section E, Crystallographic communications, International Union of Crystallography, 2017, 73 (2), pp.296-299. ⟨10.1107/S2056989017001190⟩, Acta Crystallographica Section E: Crystallographic Communications, Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 2, Pp 296-299 (2017)
- Publication Year :
- 2017
- Publisher :
- HAL CCSD, 2017.
-
Abstract
- The crystal structure of the title compound, dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate displays a conformational disorder which inverts the configuration of the chiral C atom within the cyclo­hexyl­idene ring.<br />The crystal structure and the conformation of the title compound, C22H27N3O7S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia­zolidinone derivative prepared and isolated as pure product from thio­semicarbazone carvone. The mol­ecule is built up from an oxo­thia­zolidine ring tetra­substituted by a meth­oxy–oxo­ethyl­idene, a maleate, an oxygen and a cyclo­hexyl­idene–hydrazone. The cyclo­hexyl­idene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon.
- Subjects :
- Stereochemistry
Hydrazone
Crystal structure
010403 inorganic & nuclear chemistry
Ring (chemistry)
01 natural sciences
Natural product
Research Communications
lcsh:Chemistry
chemistry.chemical_compound
General Materials Science
[CHIM.COOR]Chemical Sciences/Coordination chemistry
chemistry.chemical_classification
010405 organic chemistry
General Chemistry
Meth
Condensed Matter Physics
3. Good health
0104 chemical sciences
Thiazolidine derivatives
chemistry
lcsh:QD1-999
thiazolidine derivatives
Heterocyclic compounds
Derivative (chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 20569890
- Database :
- OpenAIRE
- Journal :
- Acta crystallographica. Section E, Crystallographic communications, Acta crystallographica. Section E, Crystallographic communications, International Union of Crystallography, 2017, 73 (2), pp.296-299. ⟨10.1107/S2056989017001190⟩, Acta Crystallographica Section E: Crystallographic Communications, Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 2, Pp 296-299 (2017)
- Accession number :
- edsair.doi.dedup.....a0eb07d535a76874c0957ea2795b50f9
- Full Text :
- https://doi.org/10.1107/S2056989017001190⟩