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IRMPD Spectroscopy of Bare Monodeprotonated Genistein, an Antioxidant Flavonoid

Authors :
Paciotti, Roberto
Chiavarino, Barbara
Coletti, Cecilia
Scuderi, Debora
Re, Nazzareno
Corinti, Davide
Rotari, Lucretia
Fornarini, Simonetta
Crestoni, Maria Elisa
Università degli studi 'G. d'Annunzio' Chieti-Pescara [Chieti-Pescara] (Ud'A)
Università degli Studi di Roma 'La Sapienza' = Sapienza University [Rome] (UNIROMA)
Institut de Chimie Physique (ICP)
Institut de Chimie du CNRS (INC)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)
European Project: 731077,H2020,H2020-INFRAIA-2017-1-two-stage, EU_FT-ICR_MS(2018)
European Project: 730872,CALIPSOplus
Source :
ACS Omega, ACS Omega, 2022, 7 (23), pp.19535-19544. ⟨10.1021/acsomega.2c01236⟩
Publication Year :
2022
Publisher :
American Chemical Society, 2022.

Abstract

Genistein is a naturally occurring polyphenol belonging to the family of flavonoids with estrogenic properties and proven antioxidant, anti-inflammatory, and hormonal effects. Genistein and its derivatives are involved in radical scavenging activity by way of mechanisms based on sequential proton-loss electron transfer. In view of this role, a detailed structural characterization of its bare deprotonated form, [geni-H]

Details

Language :
Italian
ISSN :
24701343
Database :
OpenAIRE
Journal :
ACS Omega, ACS Omega, 2022, 7 (23), pp.19535-19544. ⟨10.1021/acsomega.2c01236⟩
Accession number :
edsair.doi.dedup.....a37ffe59c126a81cc073df47424e2f01