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Effects of total suspended solids, particle size, and effluent temperature on the kinetics of peracetic acid decomposition in municipal wastewater
- Source :
- Water Science and Technology. 80:2299-2309
- Publication Year :
- 2019
- Publisher :
- IWA Publishing, 2019.
-
Abstract
- In this study, the influence of total suspended solids (TSS) and particle size as well as effluent temperature on peracetic acid (PAA) decomposition kinetics in municipal wastewater was investigated. PAA decomposition was best described following second order kinetics in primary effluent (PE) and first order kinetics in secondary effluent (SE) samples. For synthetic samples prepared by varying TSS levels, PAA demand increased on average by about 0.042 mg/L in PE and 0.034 mg/L in SE for every 10 mg/L increase in TSS. Similarly, the PAA decay rate constant in these samples increased at a rate of 0.0014 L/mg.min and 0.00039 min−1, respectively, per 10 mg/L TSS. To examine the effect of particle size, synthetic samples with narrow size fractions (20–45, 45–75, and 75–90 μm) were prepared. It was found that samples with smaller particle size fractions had a greater PAA demand and decay rate constant. Effluent temperature also enhanced the PAA decomposition rate with the calculated activation energies for PE and SE samples being 29,980 J/mol and 34,860 J/mol, respectively.
- Subjects :
- Environmental Engineering
02 engineering and technology
Wastewater
010501 environmental sciences
Waste Disposal, Fluid
01 natural sciences
chemistry.chemical_compound
Reaction rate constant
020401 chemical engineering
Peracetic acid
Peracetic Acid
Particle Size
0204 chemical engineering
Effluent
0105 earth and related environmental sciences
Water Science and Technology
Total suspended solids
Chemistry
Temperature
Decomposition
Disinfection
Kinetics
Particle size
Waste disposal
Nuclear chemistry
Subjects
Details
- ISSN :
- 19969732 and 02731223
- Volume :
- 80
- Database :
- OpenAIRE
- Journal :
- Water Science and Technology
- Accession number :
- edsair.doi.dedup.....a5e9e58cc19ce438176ce439e86f4803