Preparation of Carborane-Tailored Covalent Organic Frameworks by a Postsynthetic Modification Strategy as a Barrier to Polysulfide in Lithium-Sulfur Batteries

Lithium-sulfur batteries (LSBs) have attracted much attention due to their high energy density and theoretical specific capacity. However, the "shuttle effect" of polysulfides limits their application. Herein, we propose a postsynthetic modification (PSM) strategy to synthesize a fibrous carborane-tailored covalent organic framework (PMCB-COF). Benefiting from its amphiphilicity, strong adsorption ability, high specific surface area, and accessible Li