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Tuning the coordination sphere of octahedral Dy(<scp>iii</scp>) complexes with silanolate/stannanolate ligands: synthesis, structures and slow relaxation of the magnetization
- Source :
- CrystEngComm, CrystEngComm, Royal Society of Chemistry, 2021, 23 (47), pp.8351-8359. ⟨10.1039/D1CE01266E⟩
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- This study reports four SMMs based on silanolate or stannanolate ligands cis-[Dy(OSiPh3)2(THF)4][BPh4]·THF·C6H6 (1), cis-[Dy(OSnPh3)2(THF)4][BPh4]·THF·C6H6·C6H14 (2), fac-[Dy(OSiPh3)3(THF)3]·THF (3) and fac-[Dy(OSiPh3)3(bipy)(THF)]·THF (4).
- Subjects :
- Coordination sphere
Denticity
Materials science
010405 organic chemistry
Ligand
chemistry.chemical_element
General Chemistry
Crystal structure
010402 general chemistry
Condensed Matter Physics
01 natural sciences
0104 chemical sciences
3. Good health
chemistry.chemical_compound
Magnetization
Crystallography
Octahedron
chemistry
Dysprosium
[CHIM.COOR]Chemical Sciences/Coordination chemistry
General Materials Science
Tetrahydrofuran
Subjects
Details
- ISSN :
- 14668033
- Volume :
- 23
- Database :
- OpenAIRE
- Journal :
- CrystEngComm
- Accession number :
- edsair.doi.dedup.....a8d274f1acbd056cab85c24df18bc344
- Full Text :
- https://doi.org/10.1039/d1ce01266e