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Bis[μ-N,N'-bis(quinolin-8-yl)pyridine-2,6-dicarboxamido]dizinc(II) dichloromethane disolvate
- Source :
- Acta crystallographica. Section C, Crystal structure communications. 67(Pt 4)
- Publication Year :
- 2010
-
Abstract
- The title compound, [Zn(2)(C(25)H(15)N(5)O(2))(2)]·2CH(2)Cl(2), is a dinuclear double-helical complex which lies on a crystallographic twofold axis. In the complex, both ligands are partitioned into two tridentate domains which allow each ligand to bridge both metal centres. Each Zn(II) atom is six-coordinated in a distorted octahedral environment formed by two amide N atoms, two quinoline N atoms and two pyridine N atoms from two different ligand molecules, with the central pyridine ring, unusually, bridging two Zn(II) atoms. The deprotonated ligand is not planar, the amide side chains being considerably twisted out from the plane of the central pyridine ring.
- Subjects :
- Models, Molecular
Molecular Structure
Chemistry
Stereochemistry
Ligand
Quinoline
Hydrogen Bonding
General Medicine
Crystal structure
Ring (chemistry)
Crystallography, X-Ray
Ligands
General Biochemistry, Genetics and Molecular Biology
Crystallography
chemistry.chemical_compound
Zinc
Deprotonation
Amide
Pyridine
Organometallic Compounds
Molecule
Subjects
Details
- ISSN :
- 16005759
- Volume :
- 67
- Issue :
- Pt 4
- Database :
- OpenAIRE
- Journal :
- Acta crystallographica. Section C, Crystal structure communications
- Accession number :
- edsair.doi.dedup.....aa7fd6a1eba1639a61fefd1b74a81160