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Lack of resolvable titanium stable isotopic variations in bulk chondrites

Authors :
Zhengbin Deng
Paolo A. Sossi
Kirsten van Zuilen
Frédéric Moynier
Marc Chaussidon
Emily A. Pringle
Institut de Physique du Globe de Paris (IPGP)
Centre National de la Recherche Scientifique (CNRS)-Université de La Réunion (UR)-Université Paris Diderot - Paris 7 (UPD7)-IPG PARIS-Institut national des sciences de l'Univers (INSU - CNRS)
Inst Univ France, F-75005 Paris, France
Institut national des sciences de l'Univers (INSU - CNRS)-IPG PARIS-Université de La Réunion (UR)-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP)
Faculty of Earth and Life Sciences [Amsterdam] (FALW)
Vrije Universiteit Amsterdam [Amsterdam] (VU)
Geology and Geochemistry
Source :
Geochimica et Cosmochimica Acta, Geochimica et Cosmochimica Acta, Elsevier, 2018, 239, pp.409-419. ⟨10.1016/j.gca.2018.06.016⟩, Geochimica et Cosmochimica Acta, 239, 409-419. Elsevier Limited, Deng, Z, Moynier, F, van Zuilen, K, Sossi, P A, Pringle, E A & Chaussidon, M 2018, ' Lack of resolvable titanium stable isotopic variations in bulk chondrites ', Geochimica et Cosmochimica Acta, vol. 239, pp. 409-419 . https://doi.org/10.1016/j.gca.2018.06.016
Publication Year :
2018
Publisher :
Elsevier Limited, 2018.

Abstract

International audience; Titanium and calcium are both refractory lithophile elements. Significant stable isotopic variations on Ti and Ca have been documented within calcium, aluminum-rich inclusions (CAIs) in carbonaceous chondrites. To trace the condensation history of Ti in the solar nebula, we conducted a high-precision double-spike Ti stable isotopic study on a large set of chondrites. The studied chondrites have a homogeneous bulk Ti stable isotopic composition (delta 49/47Ti(IPGP-Ti) = -0.069 +/- 0.018 parts per thousand, 2se, n = 22, i.e., the per mil deviation of the Ti-49/Ti-47 ratios relative to the IPGP-Ti reference material). The homogeneity across eleven chondrite groups implies that chondrites have acquired, through the condensation sequence at equilibrium, the average stable isotopic composition of Ti in the refractory solids that condensed early in the solar nebula. In contrast, the light Ca stable isotopic compositions of bulk chondrites can be attributed to either the presence of CAIs (CV-, CM- and CO-type) or parent-body aqueous alteration (CR- and CI-type).

Details

Language :
English
ISSN :
00167037
Volume :
239
Database :
OpenAIRE
Journal :
Geochimica et Cosmochimica Acta
Accession number :
edsair.doi.dedup.....ab0c9464c9fcd97a432e6d6f0ce988d9