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TEMPO-mediated oxidation of polysaccharides: An ongoing story

Authors :: Yves M. Galante
Cédric Delattre
Andrea Fiorati
Carlo Punta
Lucio Melone
Nadia Pastori
Pascal Dubessay
Guillaume Pierre
Philippe Michaud
Institut Pascal (IP)
SIGMA Clermont (SIGMA Clermont)-Université Clermont Auvergne [2017-2020] (UCA [2017-2020])-Centre National de la Recherche Scientifique (CNRS)
Department of Chemistry, Materials, and Chemical Engineering 'G. Natta' and Local Unit INSTM
Politecnico di Milano [Milan] (POLIMI)
Biologie moléculaire et génome des protozoaires parasites (BMGPP)
Université Montpellier 1 (UM1)-Centre National de la Recherche Scientifique (CNRS)
Istituto di Chimica del Riconoscimento Molecolare
Università cattolica del Sacro Cuore [Milano] (Unicatt)
SIGMA Clermont (SIGMA Clermont)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne [2017-2020] (UCA [2017-2020])
Source :: Carbohydrate polymers 165 (2017): 71–85. doi:10.1016/j.carbpol.2017.02.028, info:cnr-pdr/source/autori:Pierre G.; Punta C.; Delattre C.; Melone L.; Dubessay P.; Fiorati A.; Pastori N.; Galante Y.M.; Michaud P./titolo:TEMPO-mediated oxidation of polysaccharides: An ongoing story/doi:10.1016%2Fj.carbpol.2017.02.028/rivista:Carbohydrate polymers/anno:2017/pagina_da:71/pagina_a:85/intervallo_pagine:71–85/volume:165, Carbohydrate Polymers, Carbohydrate Polymers, Elsevier, 2017, 165, pp.71-85. ⟨10.1016/j.carbpol.2017.02.028⟩, Carbohydrate Polymers, 2017, 165, pp.71-85. ⟨10.1016/j.carbpol.2017.02.028⟩
Publication Year :: 2017
Publisher :: Applied Science Publishers., London, Regno Unito, 2017.
Abstract: International audience; The oxidation of natural polysaccharides by TEMPO has become by now an “old chemical reaction” which led to numerous studies mainly conducted on cellulose. This regioselective oxidation of primary alcohol groups of neutral polysaccharides has generated a new class of polyuronides not identified before in nature, even if the discovery of enzymes promoting an analogous oxidation has been more recently reported. Around the same time, the scientific community discovered the surprising biological and techno-functional properties of these anionic macromolecules with a high potential of application in numerous industrial fields. The objective of this review is to establish the state of the art of TEMPO chemistry applied to polysaccharide oxidation, its history, the resulting products, their applications and the associated modifying enzymes.

Details

Language :: English
ISSN :: 01448617
Database :: OpenAIRE
Journal :: Carbohydrate polymers 165 (2017): 71–85. doi:10.1016/j.carbpol.2017.02.028, info:cnr-pdr/source/autori:Pierre G.; Punta C.; Delattre C.; Melone L.; Dubessay P.; Fiorati A.; Pastori N.; Galante Y.M.; Michaud P./titolo:TEMPO-mediated oxidation of polysaccharides: An ongoing story/doi:10.1016%2Fj.carbpol.2017.02.028/rivista:Carbohydrate polymers/anno:2017/pagina_da:71/pagina_a:85/intervallo_pagine:71–85/volume:165, Carbohydrate Polymers, Carbohydrate Polymers, Elsevier, 2017, 165, pp.71-85. ⟨10.1016/j.carbpol.2017.02.028⟩, Carbohydrate Polymers, 2017, 165, pp.71-85. ⟨10.1016/j.carbpol.2017.02.028⟩
Accession number :: edsair.doi.dedup.....ac498ac5593e8fb1a48fd1d91d14028c
Full Text :: https://doi.org/10.1016/j.carbpol.2017.02.028