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A new organic-inorganic hybrid based on the crescent-shaped polyoxoanion [H6SiNb18O54]8- and copper-organic cations

Authors :
Chun-Yi Sun
Hai-Ning Wang
Zhong-Min Su
Kui-Zhan Shao
Yan Xing
Peng Huang
Chao Qin
Xin-Long Wang
Source :
Dalton transactions (Cambridge, England : 2003). 41(20)
Publication Year :
2012

Abstract

A new organic-inorganic hybrid, [Cu(en)(2)](3){[Cu(en)(2)][H(6)SiNb(18)O(54)]}·22H(2)O (1, en = ethylenediamine) containing the crescent-shaped polyoxoanion [H(6)SiNb(18)O(54)](8-) and copper-organic cations has been successfully synthesized, and elemental analyses, IR spectra, thermogravimetric analyses and single-crystal X-ray diffraction were investigated.

Details

ISSN :
14779234
Volume :
41
Issue :
20
Database :
OpenAIRE
Journal :
Dalton transactions (Cambridge, England : 2003)
Accession number :
edsair.doi.dedup.....ae172c434800c81d358e02eb195d1222