A High Optical-Gain Organic Crystal Comprising Thiophene/Phenylene Co-Oligomer Nanomolecules

We have estimated the optical gain for a crystal of a thiophene/phenylene co-oligomer, 1,4-bis(5-phenylthiophen-2-yl)benzene. We prepared the crystal by a vapor phase growth method and measured emission spectra by exciting it with a pulse laser and changing the pumped stripe lengths. With increasing the stripe lengths, the emission intensity was increased and the emission spectra were gain narrowed around 516 nm with its full width at half maximum down to approximately 6 nm. The optical gain spectrum was determined from the emission spectra that varied as a function of the pumped stripe lengths. The gain spectrum was peaked at 516 nm with the maximum net optical gain coefficient being 75 cm(-1). This peak location is in excellent agreement with the peak position of the gain narrowed emission spectra. The results indicate that the determination of the gain spectrum is important for laser applications of the material. The oligomer crystal in the present studies is a good candidate for them.