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Extending Chirality in Group XIV Metallatranes
- Source :
- Inorganic Chemistry, Inorganic Chemistry, 2023, 62 (20), pp.7662-7680. ⟨10.1021/acs.inorgchem.2c04242⟩
- Publication Year :
- 2023
- Publisher :
- American Chemical Society (ACS), 2023.
-
Abstract
- International audience; The syntheses of the racemic amino alcohol racN(CH2CMe2OH)(CMe2CH2OH)(CH2CHMeOH) (L22'1*H3, 2) and its representative N(CH2CMe2OH)(CMe2CH2OH)(CH2C-(R)HMeOH) (L22'1RH3, 3) with the stereogenic carbon center being R-configured are reported. Also reported are the stannatranes L22'1*SnOt-Bu (4) L22'1RSnOt-Bu (6) and germatranes L22'1*GeOEt (5) and L22'1RGeOEt (7) as well as the trinuclear tin oxocluster [(mu 3-O)(mu 3-O-t-Bu){SnL22'1R}3] (8). NMR and IR spectroscopy, electrospray ionization mass spectrometry (ESI MS), and single crystal X-ray diffraction analysis characterize these compounds. Computational studies accompany the experimental work and help understand the diastereoselectivity observed in the course of the metallatrane syntheses.
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 62
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry
- Accession number :
- edsair.doi.dedup.....afb0a15278cd6c71907a39ea4d49a262