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Dynamics of liquids in the large-dimensional limit

Authors :
Grzegorz Szamel
Giulio Biroli
David R. Reichman
Chen Liu
Source :
Physical Review E. 104
Publication Year :
2021
Publisher :
American Physical Society (APS), 2021.

Abstract

In this paper we analytically derive the exact closed dynamical equations for a liquid with short-ranged interactions in large spatial dimensions using the same statistical mechanics tools employed to analyze Brownian motion. Our derivation greatly simplifies the original path-integral-based route to these equations and provides insight into the physical features associated with high-dimensional liquids and glass formation. Most importantly, our construction provides a route to the exact dynamical analysis of important related dynamical problems, as well as a means to devise cluster generalizations of the exact solution in infinite dimensions. This latter fact opens the door to the construction of increasingly accurate theories of vitrification in three-dimensional liquids.

Details

ISSN :
24700053 and 24700045
Volume :
104
Database :
OpenAIRE
Journal :
Physical Review E
Accession number :
edsair.doi.dedup.....b0c0e9c352c78f367c8e851bd186c656
Full Text :
https://doi.org/10.1103/physreve.104.054606