Back to Search
Start Over
Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration
- Source :
- Chemical communications (Cambridge, England). 50(57)
- Publication Year :
- 2014
-
Abstract
- A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)-C(sp(3)) and C(sp(3))-P bonds was observed.
- Subjects :
- Allylic rearrangement
Propanols
Aryl
Metals and Alloys
General Chemistry
Chemistry Techniques, Synthetic
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Phosphates
chemistry.chemical_compound
chemistry
Materials Chemistry
Ceramics and Composites
Organic chemistry
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 50
- Issue :
- 57
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....b111ecbf5da71a6ac9666ae1b3cca584