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Homoleptic gold(i) N-heterocyclic allenylidene complexes: excited-state properties and lyotropic chromonics
- Source :
- Chemical communications (Cambridge, England). 52(28)
- Publication Year :
- 2016
-
Abstract
- A series of phosphorescent Au(i) bis(N-heterocyclic allenylidene) complexes, namely [Au(=C=C=CR(1)R(2))2](+)X(-), were synthesized and structurally characterized. These organometallic complexes exhibit panchromatic transient absorption upon electronic photo-excitation and can self-organize into lyotropic chromonic mesophases in aqueous solutions.
- Subjects :
- 010402 general chemistry
Photochemistry
01 natural sciences
Catalysis
chemistry.chemical_compound
Heterocyclic Compounds
Lyotropic
Ultrafast laser spectroscopy
Materials Chemistry
Molecule
Homoleptic
Aqueous solution
Molecular Structure
010405 organic chemistry
Metals and Alloys
Water
General Chemistry
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Alkadienes
Solutions
Crystallography
chemistry
Excited state
Ceramics and Composites
Chromonic
Gold
Phosphorescence
Organogold Compounds
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 52
- Issue :
- 28
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....b19847d2470c14b4396143c75b6b128d