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1,1 '-Diphenyl-bis-germatrane with persistent radical cation

Authors :
Anna Ya. Kozmenkova
Mikhail A. Syroeshkin
Mikhail P. Egorov
Daria M. Vakhrusheva
Badma N. Mankaev
Irina V. Krylova
Viatcheslav Jouikov
Vitalijs Romanovs
Latvian Institute of Organic Synthesis
ND Zelinsky Institute of Organic Chemistry [Moscow, Russia]
Mendeleev University of Chemical Technology of Russia
Lomonosov Moscow State University (MSU)
Institut des Sciences Chimiques de Rennes (ISCR)
Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1)
Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)
Russian Science FoundationRussian Science Foundation (RSF) [18-73-10180]
European Regional Development Fund ERDF - Latvia [1.1.1.2/VIAA/3/19/577]
Latvian Institute of Organic Synthesis [Riga, Lituania]
Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Source :
Mendeleev Communications, Mendeleev Communications, Elsevier, 2020, 30 (5), pp.567-568. ⟨10.1016/j.mencom.2020.09.004⟩, Mendeleev Communications, 2020, 30 (5), pp.567-568. ⟨10.1016/j.mencom.2020.09.004⟩
Publication Year :
2020
Publisher :
HAL CCSD, 2020.

Abstract

International audience; Bis-phenyl derivative of a novel family of bis-metallatranes, 1,1'-diphenyl-bis-germatrane, was synthesized and characterized. One-electron oxidation of this compound is electrochemically and chemically reversible providing a persistent radical cation.

Details

Language :
English
ISSN :
09599436 and 1364551X
Database :
OpenAIRE
Journal :
Mendeleev Communications, Mendeleev Communications, Elsevier, 2020, 30 (5), pp.567-568. ⟨10.1016/j.mencom.2020.09.004⟩, Mendeleev Communications, 2020, 30 (5), pp.567-568. ⟨10.1016/j.mencom.2020.09.004⟩
Accession number :
edsair.doi.dedup.....b5d445babbbaacdca0b5e14be3fc1bc2
Full Text :
https://doi.org/10.1016/j.mencom.2020.09.004⟩