Photochemical Method for Generation of Linear Polyynes: [2 + 2] Cycloreversion of [4.3.2]Propellatrienes Extruding Indan

Authors :: Koichiro Naemura
Yoshito Tobe
Takashi Fujii
Source :: Scopus-Elsevier
Publication Year :: 1994
Publisher :: American Chemical Society (ACS), 1994.
Abstract: Photolysis of trienediynes (1a) and (1b) and trienetetrayne (1c) having a [4.3.2]propellane framework yielded the respective lines polyynes (2a-c) in good efficiency through [2+2] cycloreversion, extruding indan (3)

Subjects :: Propellane
chemistry.chemical_compound
chemistry
Organic Chemistry
Photodissociation
Indane
Aliphatic compound
Photochemistry

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