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Verdazyl Radical, a Building Block for a Six-Spin-Center 2p-3d-4f Single-Molecule Magnet
- Source :
- Inorganic Chemistry, Inorganic Chemistry, 2016, 55 (23), pp.12122-12125. ⟨10.1021/acs.inorgchem.6b02380⟩, Inorganic Chemistry, American Chemical Society, 2016, 55 (23), pp.12122-12125. ⟨10.1021/acs.inorgchem.6b02380⟩
- Publication Year :
- 2016
-
Abstract
- The versatile verdazyl family provides a new member as its reduced form 1,5-dimethyl-3-[3′-(hydroxymethyl)-2′-pyridine]-6-oxotetrazane (H3vdpyCH2OH). Upon oxidation and deprotonation in the presence of the acetate salts of CoII and DyIII, the vdpyCH2OH radical is able to self-assemble [(vdpyCH2O)2Co2Dy2ac8] (Hac = HO2CCH3), a 2p–3d–4f cluster displaying single-molecule-magnet properties.
- Subjects :
- 010405 organic chemistry
Chemistry
Center (category theory)
010402 general chemistry
Block (periodic table)
01 natural sciences
3. Good health
0104 chemical sciences
Inorganic Chemistry
Crystallography
chemistry.chemical_compound
Nuclear magnetic resonance
Deprotonation
Cluster (physics)
[CHIM]Chemical Sciences
[CHIM.COOR]Chemical Sciences/Coordination chemistry
Single-molecule magnet
Hydroxymethyl
Physical and Theoretical Chemistry
Spin (physics)
ComputingMilieux_MISCELLANEOUS
Subjects
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 55
- Issue :
- 23
- Database :
- OpenAIRE
- Journal :
- Inorganic chemistry
- Accession number :
- edsair.doi.dedup.....b6cf9cfd7492f01b7fcd60eb41aeeff3