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Synthesis of symmetric anhydrides using visible light-mediated photoredox catalysis
- Source :
- Organic & Biomolecular Chemistry. 10:4509
- Publication Year :
- 2012
- Publisher :
- Royal Society of Chemistry (RSC), 2012.
-
Abstract
- A new approach to anhydride formation is reported via activation of C-O bonds by the Vilsmeier-Haack reagent formed by Ru(bpy)(3)Cl(2) and CBr(4) in DMF. Various aryl and alkyl carboxylic acids are converted to the corresponding anhydrides in excellent yields.
- Subjects :
- chemistry.chemical_classification
Light
Molecular Structure
Aryl
education
Organic Chemistry
Photoredox catalysis
Photochemical Processes
Photochemistry
Biochemistry
Catalysis
humanities
Anhydrides
chemistry.chemical_compound
chemistry
Reagent
Physical and Theoretical Chemistry
Oxidation-Reduction
Alkyl
Visible spectrum
Subjects
Details
- ISSN :
- 14770539 and 14770520
- Volume :
- 10
- Database :
- OpenAIRE
- Journal :
- Organic & Biomolecular Chemistry
- Accession number :
- edsair.doi.dedup.....bad0f6bdb44984dfb0dab0e441b8b4af
- Full Text :
- https://doi.org/10.1039/c2ob25463h