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Asymmetric Chiral Ligand-Directed Alkene Dioxygenation
- Source :
- Organic Letters. 15:46-49
- Publication Year :
- 2012
- Publisher :
- American Chemical Society (ACS), 2012.
-
Abstract
- A Pd-catalyzed asymmetric alkene 1,2-dioxygenation reaction is described. The diastereoselectivity of the reaction is controlled by tethering a chiral oxime ether directing group to the alkene substrate. The best selectivities are obtained with 8-substituted menthone-derived oxime ether auxiliaries.
- Subjects :
- chemistry.chemical_classification
Chemistry
Stereochemistry
Alkene
Organic Chemistry
Chiral ligand
Substrate (chemistry)
chemistry.chemical_element
Stereoisomerism
Oxidation reduction
Alkenes
Oxime ether
Biochemistry
Catalysis
Article
Oximes
Physical and Theoretical Chemistry
Oxidation-Reduction
Palladium
Ethers
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 15
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....badff4ad7c05e2f4ed3a87006dbf3063
- Full Text :
- https://doi.org/10.1021/ol303003g