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Purification of organic acids by chromatography with strong anionic resins: Investigation of uptake mechanisms

Authors :
Marc-André Theoleyre
Julien Lemaire
Moncef Stambouli
Dominique Pareau
Florence Lutin
Claire-Line Blanc
Laboratoire de Génie des Procédés et Matériaux - EA 4038 (LGPM)
CentraleSupélec
Eurodia industrie
Source :
Journal of Chromatography A, Journal of Chromatography A, Elsevier, 2016, 1458, pp.63-69. ⟨10.1016/j.chroma.2016.06.057⟩
Publication Year :
2016
Publisher :
HAL CCSD, 2016.

Abstract

International audience; Bio-based organic acids are promising renewable carbon sources for the chemical industry. However energy-consuming purification processes are used, like distillation or crystallization, to reach high purities required in some applications. That is why preparative chromatography was studied as an alternative separation technique. In a previous work dealing with the purification of lactic, succinic and citric acids, the Langmuir model was insufficient to explain the elution profiles obtained with a strong anionic resin.Consequently the Langmuir model was coupled with a usual ion-exchange model to take into account the retention of their conjugate bases (

Details

Language :
English
ISSN :
00219673 and 18733778
Database :
OpenAIRE
Journal :
Journal of Chromatography A, Journal of Chromatography A, Elsevier, 2016, 1458, pp.63-69. ⟨10.1016/j.chroma.2016.06.057⟩
Accession number :
edsair.doi.dedup.....bc00dc23bb24ce5a6d01e7caec4ea6e5
Full Text :
https://doi.org/10.1016/j.chroma.2016.06.057⟩