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Coil Flow Inversion as a Route To Control Polymerization in Microreactors
- Source :
- Macromolecules, Macromolecules, American Chemical Society, 2014, 47 (10), pp.3282-3287. ⟨10.1021/ma5001628⟩, Macromolecules, 2014, 47 (10), pp.3282-3287. ⟨10.1021/ma5001628⟩
- Publication Year :
- 2014
- Publisher :
- HAL CCSD, 2014.
-
Abstract
- International audience; Linear and branched polymers of 2-(dimethylamino)ethyl methacrylate (PDMAEMA) were synthesized in flow by atom transfer radical polymerization (ATRP) and self-condensing vinyl copolymerization adapted to ATRP, respectively, in capillary type stainless steel coiled tube (CT) microreactors. Coil flow inversion (CFI) was introduced to achieve better mixing and narrower residence time distributions during polymerization. This strategy was adopted to improve control over macromolecular characteristics and polymer architecture. Polydispersity index (PDI), as an overall indicator of control over polymerization, was significantly lower for CFI in the case of linear PDMAEMA, 1.39 compared to 1.53 for CT. For branched polymers containing up to 10 mol % of inimer, a reduced PDI was also obtained for CFI microreactor. As for the branching efficiency, it was found to follow the following trend CFI > CT > batch reactor.
- Subjects :
- Materials science
Polymers and Plastics
Dispersity
Batch reactor
Polymer architecture
Sciences de l'ingénieur [physics]/Génie des procédés
02 engineering and technology
010402 general chemistry
Branching (polymer chemistry)
01 natural sciences
Polymerization
Inorganic Chemistry
Sciences de l'ingénieur [physics]/Milieux fluides et réactifs
Polymer chemistry
Materials Chemistry
Copolymer
Atom-transfer radical-polymerization
Organic Chemistry
Coil Flow
021001 nanoscience & nanotechnology
Microreactors
0104 chemical sciences
[CHIM.POLY]Chemical Sciences/Polymers
Chemical engineering
Microreactor
0210 nano-technology
Chimie/Polymères
Subjects
Details
- Language :
- English
- ISSN :
- 00249297 and 15205835
- Database :
- OpenAIRE
- Journal :
- Macromolecules, Macromolecules, American Chemical Society, 2014, 47 (10), pp.3282-3287. ⟨10.1021/ma5001628⟩, Macromolecules, 2014, 47 (10), pp.3282-3287. ⟨10.1021/ma5001628⟩
- Accession number :
- edsair.doi.dedup.....bd9ac6719a200e331a7135f4496959d0