An Organocatalytic Two‐atom Ring Expansion Approach to Optically Active Glutarimides

Authors :: Damien Mailhol
Yun‐Long Wei
Yoann Coquerel
Jean Rodriguez
Michel Rajzmann
Yajun Ren
Institut des Sciences Moléculaires de Marseille (ISM2)
Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
ANR-07-BLAN-0269,SYNTHECO,Target-oriented eco-conception of synthetic organic strategies(2007)
Source :: Advanced Synthesis and Catalysis, Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2019, 361, pp.2992-3001. ⟨10.1002/adsc.201900159⟩, Advanced Synthesis and Catalysis, 2019, 361, pp.2992-3001. ⟨10.1002/adsc.201900159⟩
Publication Year :: 2019
Publisher :: Wiley, 2019.
Abstract: International audience; An original two-step organocatalytic syn- thesis of optically active glutarimides from 2- oxocyclobutane carboxamides is described featuring an isothiourea-catalyzed two-atom ring-expansive rearrangement.

Subjects :: Organocatalysis
[CHIM.ORGA]Chemical Sciences/Organic chemistry
010405 organic chemistry
Chemistry
Nitrogen heterocycles
Atom (order theory)
Rearrangement
Ring expansion
Strained molecules
[CHIM.CATA]Chemical Sciences/Catalysis
General Chemistry
Optically active
010402 general chemistry
Ring (chemistry)
01 natural sciences
0104 chemical sciences
Crystallography

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