Functionalized Porous Aromatic Frameworks as High-Performance Adsorbents for the Rapid Removal of Boric Acid from Water

This study demonstrates that functionalized, highly porous polymers are promising for the adsorptive capture of boric acid, a neutral contaminant that is difficult to remove from seawater using conventional reverse osmosis membranes. Appending N-methyl-d-glucamine (NMDG) to the pore walls of high-surface-area porous aromatic frameworks (PAFs) yields the adsorbents PAF-1-NMDG and P2-NMDG in a simple two-step synthesis. The boron-selective PAFs demonstrate adsorption capacities that are up to 70% higher than those of a commercial boron-selective resin, Amberlite IRA743, and markedly faster adsorption rates, owing to their higher NMDG loadings and greater porosities relative to the resin. Remarkably, PAF-1-NMDG is able to reduce the boron concentration in synthetic seawater from 2.91 to