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Visible-Light-Induced Direct Photocatalytic Carboxylation of Indoles with CBr4 /MeOH
- Source :
- Chemistry (Weinheim an der Bergstrasse, Germany). 21(50)
- Publication Year :
- 2015
-
Abstract
- Photocatalysis enables the cascade reactions of indoles and CBr4 in MeOH through a C(sp(2) )H functionalization/methanolysis sequence. The title reaction provides an efficient access to indole 2- and 3-carboxylates in a single operation (no preinstallation of protecting as well as directing groups was required) with good yields under mild reaction conditions.
Details
- ISSN :
- 15213765
- Volume :
- 21
- Issue :
- 50
- Database :
- OpenAIRE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Accession number :
- edsair.doi.dedup.....c33f0c06c273487f5b77a439ce29d793