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Dynamic complexation of copper(I) chloride by carbene-stabilized disilicon
- Source :
- Chemistry (Weinheim an der Bergstrasse, Germany). 20(30)
- Publication Year :
- 2014
-
Abstract
- Reaction of N-heterocyclic-carbene (NHC)-stabilized disilicon (1) with CuCl gave a carbene-stabilized disilicon-copper(I) chloride complex (2). The nature of the structure and bonding in 2 has been investigated by crystallographic, spectroscopic, and computational methods. The dynamic complexation behavior of 2 was experimentally explored by variable-temperature NMR analysis.
Details
- ISSN :
- 15213765
- Volume :
- 20
- Issue :
- 30
- Database :
- OpenAIRE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Accession number :
- edsair.doi.dedup.....c38fdd3e6444eb523077b927cf4b7f1d