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Solid-state NMR study of Schiff base derivatives of 2-hydroxynaphthaldehyde. Deuterium isotope effects on 15N chemical shifts in the solid state
- Source :
- Magnetic resonance in chemistry : MRC. 43(7)
- Publication Year :
- 2005
-
Abstract
- Schiff base derivatives of 2-hydroxynaphthylaldehyde were studied by means of 13C and 15N cross-polarization magic angle spinning NMR spectroscopy and deuterium isotope effects on 15N chemical shifts, deltaN(D), in the solid state. DeltaN(D) in the solid state provided evidenced for the presence of a dynamic proton transfer equilibrium in the solid state at the room temperature.
- Subjects :
- Deuterium NMR
Aldehydes
Carbon Isotopes
Magnetic Resonance Spectroscopy
Nitrogen Isotopes
Carbon-13 NMR satellite
Chemistry
Analytical chemistry
Hydrogen Bonding
General Chemistry
Fluorine-19 NMR
Nuclear magnetic resonance spectroscopy
Carbon-13 NMR
Naphthalenes
Deuterium
Solid-state nuclear magnetic resonance
Isomerism
Kinetic isotope effect
Magic angle spinning
General Materials Science
Protons
Nuclear Experiment
Schiff Bases
Subjects
Details
- ISSN :
- 07491581
- Volume :
- 43
- Issue :
- 7
- Database :
- OpenAIRE
- Journal :
- Magnetic resonance in chemistry : MRC
- Accession number :
- edsair.doi.dedup.....c3bc8950d7998f382bdd523551d90e9f