Metal-free oxidative C(sp3)-H bond functionalization of alkanes and conjugate addition to chromones

Authors :: Jianlin Han
Yi Pan
Ping Qian
Jincan Zhao
Hong Fang
Source :: Organic letters. 16(20)
Publication Year :: 2014
Abstract: A metal-free oxidative C(sp(3))-H bond functionalization and subsequent conjugate addition reaction using di-tert-butyl peroxide (DTBP) as the oxidant was established, which tolerates a wide range of simple alkane substrates to react with different substituted chromones for direct preparation of 2-alkylchromanones.

Subjects :: Alkane
chemistry.chemical_classification
Addition reaction
Chemistry
Hydrogen bond
Organic Chemistry
Oxidative phosphorylation
Biochemistry
Peroxide
chemistry.chemical_compound
Metal free
Polymer chemistry
Surface modification
Organic chemistry
Physical and Theoretical Chemistry
Conjugate

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