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Continental and Ecoregion‐Specific Drivers of Atmospheric NO 2 and NH 3 Seasonality Over Africa Revealed by Satellite Observations

Authors :
Kostas Tsigaridis
Martin Van Damme
Jonathan E. Hickman
Lieven Clarisse
Enrico Dammers
Money Ossohou
Susanne E. Bauer
Niels Andela
Corinne Galy-Lacaux
Laboratoire d'aérologie (LAERO)
Université Toulouse III - Paul Sabatier (UT3)
Université de Toulouse (UT)-Université de Toulouse (UT)-Observatoire Midi-Pyrénées (OMP)
Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3)
Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)
Source :
Global Biogeochemical Cycles, Global Biogeochemical Cycles, 2021, 35, ⟨10.1029/2020GB006916⟩
Publication Year :
2021
Publisher :
American Geophysical Union (AGU), 2021.

Abstract

International audience; Ammonia (NH3) and nitrogen oxides (NOx: nitrogen dioxide [NO2] + nitric oxide [NO]) play important roles in atmospheric chemistry. Throughout most of Africa, emissions of these gases are predominantly from soils and biomass burning. Here we use observations of tropospheric NO2 vertical column densities (VCDs) from the Ozone Monitoring Instrument from 2005 through 2017 and atmospheric NH3 VCDs from the Infrared Atmospheric Sounding Interferometer from 2008 through 2017 to evaluate seasonal variation of NO2 and NH3 VCDs across Africa and in seven African ecoregions. In regions where mean annual precipitation (MAP) is under 500 mm yr−1, we find that NO2 and NH3 VCDs are positively related to monthly precipitation, and where MAP is between 500 and 1,750 mm yr−1 or higher, NO2 VCDs are negatively related to monthly precipitation. In dry ecoregions, temperature and precipitation were important predictors of NH3 and NO2 VCDs, likely related to variation in soil emissions. In mesic ecoregions, monthly NO2 VCDs were strongly related to burned area, suggesting that biomass burning drives seasonality. NH3 VCDs in mesic ecoregions were positively related to both monthly temperature and monthly carbon monoxide (CO) VCDs, suggesting that a mixture of soil and biomass burning emissions influenced NH3 seasonality. In northern mesic ecoregions, monthly temperature explained most of the variance in monthly NH3 VCDs, suggesting that soil sources, including animal excreta, determined NH3 seasonality. In southern mesic ecoregions, monthly CO VCDs explained more variation in NH3 VCDs than temperature, suggesting that biomass burning may have greater influence over NH3 seasonality.

Details

ISSN :
19449224 and 08866236
Volume :
35
Database :
OpenAIRE
Journal :
Global Biogeochemical Cycles
Accession number :
edsair.doi.dedup.....c72a964f9fbfd930fd33fd5eb3244886
Full Text :
https://doi.org/10.1029/2020gb006916