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Synthesis, reactivity, and some photochemistry of ortho-N,N-dimethylaminomethyl substituted aryl and ferrocenyl pentamethylcyclopentadienyl dicarbonyl iron complexes
- Source :
- Journal of Organometallic Chemistry, Journal of Organometallic Chemistry, 2013, 741-742, pp.47-58. ⟨10.1016/j.jorganchem.2013.05.031⟩, Journal of Organometallic Chemistry, Elsevier, 2013, 741-742, pp.47-58. ⟨10.1016/j.jorganchem.2013.05.031⟩
- Publication Year :
- 2013
- Publisher :
- Elsevier BV, 2013.
-
Abstract
- Supplementary materials: CCDC 928736, 928273, 928738, 928275, 928274 and 928737 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif; International audience; Ortho-lithiated N,N-dimethylaminomethyl ferrocene and benzyldimethylamine react with Cp*Fe(CO)2I to give the new complexes ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H3)Fe(Cp) and Cp*Fe(CO)2-C6H4(o-CH2NMe2). Access to a wide variety of alkoxy-substituted complexes ((Cp*Fe(CO)2)-2-(CH2OR)C5H3)Fe(Cp) can be easily achieved by tandem quaternization/alcoholysis of ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H3)Fe(Cp). Preliminary results show that chelated complexes can be obtained by displacement of one of the carbonyl ligands by photolysis. Crystal structures of ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H3)Fe(Cp), ((Cp*Fe(CO)2)-2-(CH2OR)C5H3)Fe(Cp) (R = Ph, Bz, CHPh2 and d-menthyl) and [Cp*Fe(CO)2-C6H4(o-CH2NMe2)][I] are reported.
- Subjects :
- 010405 organic chemistry
Aryl
Organic Chemistry
Photodissociation
Crystal structure
Iron complexes
010402 general chemistry
Photochemistry
01 natural sciences
Biochemistry
0104 chemical sciences
3. Good health
Alcoholysis
Inorganic Chemistry
chemistry.chemical_compound
Ferrocene
chemistry
Materials Chemistry
Chelation
Iron complex
Reactivity (chemistry)
Ferrocenes
Physical and Theoretical Chemistry
[CHIM.OTHE]Chemical Sciences/Other
Piano-stool structures
Subjects
Details
- ISSN :
- 0022328X
- Database :
- OpenAIRE
- Journal :
- Journal of Organometallic Chemistry
- Accession number :
- edsair.doi.dedup.....c936ef1497d65f0d831144fda5770aa1