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Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes
- Source :
- Dalton transactions (Cambridge, England : 2003). 48(17)
- Publication Year :
- 2019
-
Abstract
- Phosphines react with the benzisothiazolinate (bit) paddlewheel dimer, [Ni2(μ-bit)4·2H2O], resulting in sulfur–nitrogen bond scission and a series of unexpected transformations leading to novel Ni(ii) complexes containing 2-cyanophenylthiolate and related thiolate ligands.
Details
- ISSN :
- 14779234
- Volume :
- 48
- Issue :
- 17
- Database :
- OpenAIRE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Accession number :
- edsair.doi.dedup.....c9957b7501c88a29e24aaaf4719db915