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Crystal structure oftrans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data

Authors :
Jong-Ha Choi
Dohyun Moon
Source :
Acta Crystallographica Section E: Crystallographic Communications, Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 12, Pp 1872-1874 (2016)
Publication Year :
2016
Publisher :
International Union of Crystallography (IUCr), 2016.

Abstract

In the title compound, (C6H16N2)[CrO4], the trans-cyclo­hexane-1,2-di­ammonium cations and chromate anions are connected through N—H⋯O hydrogen bonds. The tetra­hedral CrO4 2− anion is slightly distorted due to the influence of the hydrogen bonds.<br />The structure of the title hybrid compound, (C6H16N2)[CrO4], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO4 2− anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding inter­actions with neighbouring trans-cyclo­hexane-1,2-di­ammonium cations, whereby the two Cr—O bonds to the O atoms acting as acceptor atoms for two hydrogen bonds are slightly longer than the other two Cr—O bonds for which only one acceptor inter­action per O atom is observed. In the crystal, cations and anions are packed into layers parallel to (001), held together through the aforementioned N—H⋯O hydrogen bonds.

Details

ISSN :
20569890
Volume :
72
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Crystallographic Communications
Accession number :
edsair.doi.dedup.....cacd9f850ac8758096ce7e65d6a0afc3