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Crystal structure oftrans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data
- Source :
- Acta Crystallographica Section E: Crystallographic Communications, Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 12, Pp 1872-1874 (2016)
- Publication Year :
- 2016
- Publisher :
- International Union of Crystallography (IUCr), 2016.
-
Abstract
- In the title compound, (C6H16N2)[CrO4], the trans-cyclo­hexane-1,2-di­ammonium cations and chromate anions are connected through N—H⋯O hydrogen bonds. The tetra­hedral CrO4 2− anion is slightly distorted due to the influence of the hydrogen bonds.<br />The structure of the title hybrid compound, (C6H16N2)[CrO4], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO4 2− anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding inter­actions with neighbouring trans-cyclo­hexane-1,2-di­ammonium cations, whereby the two Cr—O bonds to the O atoms acting as acceptor atoms for two hydrogen bonds are slightly longer than the other two Cr—O bonds for which only one acceptor inter­action per O atom is observed. In the crystal, cations and anions are packed into layers parallel to (001), held together through the aforementioned N—H⋯O hydrogen bonds.
- Subjects :
- crystal structure
Cyclohexane conformation
Crystal structure
010402 general chemistry
010403 inorganic & nuclear chemistry
01 natural sciences
Research Communications
Ion
Crystal
chemistry.chemical_compound
Atom
trans-cyclohexane-1,2-diammonium
General Materials Science
trans-cyclohexane-1,2-diammonium
hybrid compound
chromate(VI)
Crystallography
synchrotron radiation
Hydrogen bond
General Chemistry
hydrogen bonding
Condensed Matter Physics
Acceptor
0104 chemical sciences
chemistry
QD901-999
Ammonium chromate
Subjects
Details
- ISSN :
- 20569890
- Volume :
- 72
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Crystallographic Communications
- Accession number :
- edsair.doi.dedup.....cacd9f850ac8758096ce7e65d6a0afc3