Two cyclometalated Pt(<scp>ii</scp>) complexes showing reversible phosphorescence switching due to grinding-induced destruction and crystallization-induced formation of supramolecular dimer structure

Two Pt(ii) complexes 1 and 2 reveal similar supramolecular dimer structure, in which two [Pt(dfppy/ppy)(pbdtmi)]+ cations connect each other through the π⋯π stacking interaction. Thus these complexes show reversible phosphorescence switching by grinding and crystallization with toluene.