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Divergent Synthesis of Dihydroxanthene-Hemicyanine Fused Near-Infrared Fluorophores through the Late-Stage Amination of a Bifunctional Precursor
- Source :
- Organic Letters, Organic Letters, American Chemical Society, 2016, 18 (19), pp.5122-5125. 〈http://pubs.acs.org/doi/full/10.1021/acs.orglett.6b02564〉. 〈10.1021/acs.orgiett.6b02564〉, Organic Letters, American Chemical Society, 2016, 18 (19), pp.5122-5125. ⟨10.1021/acs.orgiett.6b02564⟩
- Publication Year :
- 2016
-
Abstract
- International audience; A late-stage amination of a bifunctional dihydroxanthene (DHX) scaffold is reported to access a wide variety of new near-infrared (NIR) chromophores/fluorophores. The divergent approach allows the coupling of aliphatic and aromatic amines and readily provides molecular diversity shedding light on the structure fluorescence relationship of this emerging class of NIR fluorophores.
- Subjects :
- design
010402 general chemistry
Photochemistry
01 natural sciences
Biochemistry
in-vivo
dyes
[ CHIM ] Chemical Sciences
photoinduced electron-transfer
fluorescent-probes
chemistry.chemical_compound
[ CHIM.ORGA ] Chemical Sciences/Organic chemistry
[CHIM]Chemical Sciences
spectroscopic properties
Physical and Theoretical Chemistry
Bifunctional
Amination
[CHIM.ORGA]Chemical Sciences/Organic chemistry
010405 organic chemistry
Organic Chemistry
Near-infrared spectroscopy
Late stage
unique
library
emerging applications
Chromophore
0104 chemical sciences
chemistry
Divergent synthesis
living cells
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 18
- Issue :
- 19
- Database :
- OpenAIRE
- Journal :
- Organic letters
- Accession number :
- edsair.doi.dedup.....cc350dbd85ccf2d690f796f1e0500a08
- Full Text :
- https://doi.org/10.1021/acs.orglett.6b02564〉.