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Construction of Zeolite-Like Cluster Organic Frameworks from 3 d-4 d/3 d-3 d Heterometallic Supertetrahedral Secondary Building Units: Syntheses, Structures, and Properties
- Source :
- Chemistry - A European Journal. 24:251-258
- Publication Year :
- 2017
- Publisher :
- Wiley, 2017.
-
Abstract
- Two zeolite-like cluster organic frameworks based on Cd-Cu/Mn-Cu heterometallic supertetrahedral secondary building units have been successfully constructed under solvothermal conditions, namely, Cu[Cd4Cu6(L)4(H2O)18](Ac)9⋅DMA⋅3 H2O (1), and Cu[Mn4Cu6(L)4(Ac)3(H2O)12](Ac)6⋅CH3CN⋅13 H2O (2), where H3L=2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol, Ac=CH3COO−, DMA=N,N′-dimethylacetamide. Single-crystal X-ray structural analysis reveals that both 1 and 2 exhibit 3-dimensional zeolite-like architectures with similar 4-connected components, but possess definitely different topologies of diamondoid (dia) and uncommon lonsdaleite (lon), respectively. 1 and 2 represent the first cases of zeolite-like cluster organic frameworks containing Cd-Cu/Mn-Cu heterometallic supertetrahedral secondary building units. Furthermore, the magnetic properties and porous nature of 1 and 2 were also studied.
- Subjects :
- Chemistry
Organic Chemistry
Lonsdaleite
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
Diamondoid
01 natural sciences
Catalysis
0104 chemical sciences
Crystallography
chemistry.chemical_compound
Cluster (physics)
Hydroxymethyl
0210 nano-technology
Zeolite
Subjects
Details
- ISSN :
- 09476539
- Volume :
- 24
- Database :
- OpenAIRE
- Journal :
- Chemistry - A European Journal
- Accession number :
- edsair.doi.dedup.....cfc4b169c4b1c6e255257430e70fbd41