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Cyclometalated Iridium(III) Complexes Containing 2-Phenylbenzo[d]oxazole Ligand: Synthesis, X-ray Crystal Structures, Properties and DFT Calculations
- Source :
- Acta Chimica Slovenica, Vol 66, Iss 2, Pp 378-384 (2019)
- Publication Year :
- 2019
- Publisher :
- Slovenian Chemical Society, 2019.
-
Abstract
- Two new iridium(III) complexes were synthesized and fully characterized, [(bo)2Ir(pzpy)] (2a) and [(bo)2Ir(pzpyz)] (2b) (where bo = 2-phenylbenzo[d]oxazole, pzpy = 2-(1H-pyrazol-3-yl)pyridine, pzpyz = 2-(1H-pyrazol-3-yl)pyrazine). The single crystal structures of 2a-2b have been determined. Considering the relationship between their structures and photophysical properties, DFT calculations have been used to further support this inference. These Ir(III) complexes emit from the excited state of 3MLCT/3LLCT in the green and yellow region, and the quantum yields in the degassed CH2Cl2 solution at room temperature are 35.2% and 46.1%. Theoretical and experimental results show that iridium(III) complexes 2a-2b are promising phosphorescent material.
- Subjects :
- Materials science
Pyrazine
010405 organic chemistry
Crystal structure
chemistry.chemical_element
DFT calculation
Iridium(III) complex
01 natural sciences
0104 chemical sciences
lcsh:Chemistry
Crystallography
chemistry.chemical_compound
2-phenylbenzo[d]oxazole
chemistry
lcsh:QD1-999
Excited state
Pyridine
General Earth and Planetary Sciences
Iridium
Phosphorescence
Single crystal
Photoluminescence
General Environmental Science
Oxazole
Subjects
Details
- Language :
- English
- ISSN :
- 15803155 and 13180207
- Volume :
- 66
- Issue :
- 2
- Database :
- OpenAIRE
- Journal :
- Acta Chimica Slovenica
- Accession number :
- edsair.doi.dedup.....d029b5d6eae1de6b1acb58ce137fc711