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Analytical Solution of Free Radical Polymerization: Applications- Implementing Gel Effect Using AK Model
- Source :
- Macromolecules, Macromolecules, 2014, 47 (21), pp.7370-7377. ⟨10.1021/ma501413m⟩, Macromolecules, American Chemical Society, 2014, 47 (21), pp.7370-7377. ⟨10.1021/ma501413m⟩
- Publication Year :
- 2014
- Publisher :
- HAL CCSD, 2014.
-
Abstract
- In this work, gel/glass/cage effects using the Achillias and Kiparissides (AK) model has been incorporated in the analytical solution (AS) obtained in our previous work. The AK model is based on the Chiu, Carratt, and Soong (CCS) model and free volume theory. The results of AS matched quite well with the numerical solutions as well as with the experimental data for methyl methacrylate (MMA). Various variables like termination kinetic coefficient, initiator efficiency, macroradicals concentration profile matched with the established published results. The work clearly demonstrates that AS is sufficiently flexible to accommodate gel/glass/cage effects explicitly although it was not primarily derived for these conditions. This extends the practical usage of AS for the whole range of conversion under isothermal conditions.
- Subjects :
- Work (thermodynamics)
Polymers and Plastics
Free volume theory
[SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering
Organic Chemistry
Radical polymerization
Thermodynamics
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Isothermal process
0104 chemical sciences
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Polymer chemistry
Kinetic coefficient
Materials Chemistry
[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering
Methyl methacrylate
0210 nano-technology
AK model
Subjects
Details
- Language :
- English
- ISSN :
- 00249297 and 15205835
- Database :
- OpenAIRE
- Journal :
- Macromolecules, Macromolecules, 2014, 47 (21), pp.7370-7377. ⟨10.1021/ma501413m⟩, Macromolecules, American Chemical Society, 2014, 47 (21), pp.7370-7377. ⟨10.1021/ma501413m⟩
- Accession number :
- edsair.doi.dedup.....d3525e5aba44d57ee6b3f79b4a68f18a