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Synthesis of neutral Li-endohedral PCBM: an n-dopant for fullerene derivatives

Authors :
Hiroshi Ueno
Daiki Kitabatake
Hao-Sheng Lin
Yue Ma
Il Jeon
Seiichiro Izawa
Masahiro Hiramoto
Fuminori Misaizu
Shigeo Maruyama
Yutaka Matsuo
Source :
Chemical Communications. 58:10190-10193
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

Li@PCBM was synthesized. It exists in a monomer-dimer equilibrium in solution but as a monomer in the PCBM matrix. The fully dispersed Li@PCBM served as an n-dopant for the surrounding empty PCBM, raising the Fermi level by 0.13 eV.

Subjects

Subjects :
Materials Chemistry
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials

Details

ISSN :
1364548X and 13597345
Volume :
58
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....d3a80cb6ceffed797474571522cac25f
Full Text :
https://doi.org/10.1039/d2cc03678a
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