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A single-chain magnet based on linear [MnIII2MnII] units
- Source :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2014, 50, pp. 14873-14876. ⟨10.1039/c4cc05687f⟩, Chem.Commun.
- Publication Year :
- 2014
- Publisher :
- HAL CCSD, 2014.
-
Abstract
- The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn-carboxylate SCM with a linear architecture. This journal is © the Partner Organisations 2014. 50 94 14873 14876 Cited By :8
- Subjects :
- crystal structure
Materials science
synthesis
Coordination polymer
polymer
magnetic field
anisotropy
Single chain
ligand
010402 general chemistry
01 natural sciences
Article
Catalysis
chemistry.chemical_compound
Materials Chemistry
temperature dependence
methanol
hydrogen bond
010405 organic chemistry
Metals and Alloys
single chain magnet
General Chemistry
[CHIM.MATE]Chemical Sciences/Material chemistry
magnet
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Characterization (materials science)
hysteresis
chemistry
Mixed valent
Chemical physics
magnetism
Magnet
chemical structure
manganese
Ceramics and Composites
carboxylic acid
Energy (signal processing)
Subjects
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2014, 50, pp. 14873-14876. ⟨10.1039/c4cc05687f⟩, Chem.Commun.
- Accession number :
- edsair.doi.dedup.....d3d882136f8ae92ce87ba2d68b4a6db3
- Full Text :
- https://doi.org/10.1039/c4cc05687f⟩