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A single-chain magnet based on linear [MnIII2MnII] units

Authors :
Papatriantafyllopoulou, Constantina
Zartilas, Sotiris M.
Manos, Manolis J.
Pichon, C.
Tasiopoulos, Anastasios J.
Clérac, R.
Department of Chemistry, University of Cyprus
Centre de recherches Paul Pascal (CRPP)
Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Tasiopoulos, Anastasios J. [0000-0002-4804-3822]
Papatriantafyllopoulou, Constantina [0000-0002-5652-7747]
Source :
Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2014, 50, pp. 14873-14876. ⟨10.1039/c4cc05687f⟩, Chem.Commun.
Publication Year :
2014
Publisher :
HAL CCSD, 2014.

Abstract

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn-carboxylate SCM with a linear architecture. This journal is © the Partner Organisations 2014. 50 94 14873 14876 Cited By :8

Details

Language :
English
ISSN :
13597345 and 1364548X
Database :
OpenAIRE
Journal :
Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2014, 50, pp. 14873-14876. ⟨10.1039/c4cc05687f⟩, Chem.Commun.
Accession number :
edsair.doi.dedup.....d3d882136f8ae92ce87ba2d68b4a6db3
Full Text :
https://doi.org/10.1039/c4cc05687f⟩