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Employing PCBTDPP as an Efficient Donor Polymer for High Performance Ternary Polymer Solar Cells
- Source :
- Polymers, Vol 11, Iss 9, p 1423 (2019), Polymers, Volume 11, Issue 9
- Publication Year :
- 2019
- Publisher :
- MDPI AG, 2019.
-
Abstract
- A compatible low-bandgap donor polymer (poly[N-90-heptadecanyl-2,7carbazole-alt-3,6-bis(thiophen-5-yl)-2,5-dioctyl-2,5-dihydropyrrolo[3,4]pyrrole-1,4-dione], PCBTDPP) was judicially introduced into the archetypal poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PC61BM) photoactive system to fabricate highly efficient ternary based bulk heterojunction polymer solar cells (PSCs). The PCBTDPP ternary-based PSC with optimal loading (0.2 wt.%) displayed outstanding performance with a champion power conversion efficiency (PCE) of 5.28% as compared to the PCE (4.67%) for P3HT:PC61BM-based PSC (reference). The improved PCE for PCBTDPP ternary-based PSC can be mainly attributed to the incorporation of PCBTDPP into P3HT:PC61BM that beneficially improved the optical, morphological, electronic, and photovoltaic (PV) performance. This work instills a rational strategy for identifying components (donor/acceptor (D/A) molecules) with complementary beneficial properties toward fabricating efficient ternary PSCs.
- Subjects :
- chemistry.chemical_classification
Materials science
Polymers and Plastics
Photovoltaic system
Energy conversion efficiency
General Chemistry
Polymer
ternary
low-bandgap
Acceptor
Polymer solar cell
Article
lcsh:QD241-441
Chemical engineering
chemistry
lcsh:Organic chemistry
PCBTDPP
Molecule
Ternary operation
polymer solar cells
Subjects
Details
- Language :
- English
- ISSN :
- 20734360
- Volume :
- 11
- Issue :
- 9
- Database :
- OpenAIRE
- Journal :
- Polymers
- Accession number :
- edsair.doi.dedup.....d465f72b102253d90b159278f8bfce50