Direct immersion dual-drop microextraction for simultaneous separation and enrichment of Cr(III) and Cr(IV) in food samples prior to graphite furnace atomic absorption spectrometry detection

Non-chromatographic speciation methods generally involve speciation conversion, which may cause sample contamination, analysis errors and tedious operations. In this work, a direct immersion dual-drop microextraction (DIDDME) was firstly developed for separation and preconcentration of Cr(III) and Cr(VI). In DIDDME, two organic drops on needle tips of microsyringes were concurrently immersed in a stirred sample solution. Each drop contains a chelating reagent for reacting with a specific species. Thus, Cr(III) and Cr(VI) were selectively extracted into different drops. This method afforded detection limits of 3.0 and 4.1 ng/L, quantification limitof 10 ng/L and 14 ng/L, linear range of 0.01-30 ng mL