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Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water
- Source :
- Chemical Communications. 55:11735-11738
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry (RSC), 2019.
-
Abstract
- The first two inorganic-organic hybrid three-dimensional (3D) polyoxotantalates (POTas) and the first two inorganic-organic hybrid 2D POTas have been obtained. All of these high-dimensional POTas are built from a new-type POTa dimeric cluster {Cu(en)(Ta6O19)}2/{Cu(enMe)(Ta6O19)}2 (en = ethylenediamine, enMe = 1,2-diaminopropane) bridged by copper complexes. Interestingly, extended POTas 1 and 3 can undergo single-crystal to single-crystal structural transformations triggered by water.
- Subjects :
- 010405 organic chemistry
Metals and Alloys
chemistry.chemical_element
Ethylenediamine
General Chemistry
High dimensional
010402 general chemistry
01 natural sciences
Copper
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Crystallography
chemistry
Materials Chemistry
Ceramics and Composites
Cluster (physics)
Inorganic organic
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 55
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....d773475a66d4f5ab83ff520b7908bec9