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synthesis of N-protected alpha-amino aldehydes from their morpholine amide derivatives

Authors :
Annie Heitz
Jean-Alain Fehrentz
Céline Douat
Jean Martinez
Laboratoire des Amino-acides Peptides et Protéines (LAPP)
Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Centre National de la Recherche Scientifique (CNRS)
Centre de Biochimie Structurale [Montpellier] (CBS)
Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Institut National de la Santé et de la Recherche Médicale (INSERM)
Source :
Tetrahedron Letters, Tetrahedron Letters, Elsevier, 2000, 41, pp.37-40. ⟨10.1016/S0040-4039(99)01818-3⟩
Publication Year :
2000
Publisher :
HAL CCSD, 2000.

Abstract

A new method for the synthesis of N -protected α-amino aldehydes was developed. N -Protected α-amino amides of morpholine were easily prepared and then reduced with LiAlH 4 to produce clean N -protected α-amino aldehydes. This new scheme of synthesis can be used with Boc, Z and Fmoc amino-protecting groups.

Details

Language :
English
ISSN :
00404039
Database :
OpenAIRE
Journal :
Tetrahedron Letters, Tetrahedron Letters, Elsevier, 2000, 41, pp.37-40. ⟨10.1016/S0040-4039(99)01818-3⟩
Accession number :
edsair.doi.dedup.....db5e3adac8676a2f3c99cd5f1ab8cabc